catena-Poly[[silver(I)-μ-N-(3-pyridylmethyl)pyridine-4-carboxamide] nitrate monohydrate]
نویسندگان
چکیده
In the title compound, {[Ag(C(12)H(11)N(3)O)]NO(3)·H(2)O}(n), the Ag atom is coordinated by two N atoms from the heterocyclic ligand, giving a linear polycationic chain. Two long Ag⋯O(nitrate) inter-actions [2.667 (3) and 2.840 (3) Å] result in a three-dimensional network. The water mol-ecule consolidates the network structure by forming hydrogen bonds, one to the polycationic chain and one to the nitrate anion.
منابع مشابه
catena-Poly[[silver(I)-μ-[N-(4-pyridylmethyl)pyridine-4-carboxamide-κ2 N:N′]] nitrate monohydrate]
The title coordination polymer, {[Ag(C(12)H(11)N(3)O)]NO(3)·H(2)O}(n), has a polycationic chain motif in which the Ag atom is bridged by the heterocyclic ligand; the Ag atom shows linear coordination. If the two long Ag⋯O(nitrate) inter-actions [2.794 (6) and 2.867 (5) Å] are regarded as bonds, the compound adopts a three-dimensional network structure. The water mol-ecule consolidates the netwo...
متن کاملThe silver(I) nitrate complex of the ligand N-(pyridin-2-ylmethyl)pyrazine-2-carboxamide: a metal–organic framework (MOF) structure
The reaction of silver(I) nitrate with the mono-substituted pyrazine carboxamide ligand, N-(pyridin-2-ylmeth-yl)pyrazine-2-carboxamide (L), led to the formation of the title compound with a metal-organic framework (MOF) structure, [Ag(C11H10N4O)(NO3)] n , poly[μ-nitrato-[μ-N-(pyridin-2-ylmethyl-κN)pyrazine-2-carboxamide-κN4]silver(I)]. The silver(I) atom is coordinated by a pyrazine N atom, a p...
متن کاملCrystal structure of a one-dimensional looped-chain silver(I) coordination polymer: catena-poly[[silver(I)-bis{μ-4-[1-(5′-isopropyl-[1,1′:3′,1′′-terphenyl]-2′-yl)-1H-imidazol-2-yl]pyridine-κ2 N:N′}] nitrate methanol monosolvate monohydrate]
In the title compound, {[Ag(C29H25N3)2]NO3·CH3OH·H2O} n , the Ag(I) cation is four-coordinated by two pyridine N atoms and two imidazole N atoms from four individual 4-(1-(5'-isopropyl-[1,1':3',1''-terphen-yl]-2'-yl)-1H-imidazol-2-yl)pyridine (i-pro-pyim) ligands. This gives rise to a highly distorted tetra-hedral geometry with bond angles falling in the range 100.33 (19)-122.76 (19)°. Two crys...
متن کاملcatena-Poly[[silver(I)-μ-dipyrazin-2-ylamine] perchlorate monohydrate]
In the title complex, {[Ag(C(8)H(7)N(5))]ClO(4)·H(2)O}(n), the multidentate dipyrazin-2-ylamine acts as a μ(2)-bridging link with an anti-syn configuration, assembling the Ag(I) ions into a zigzag chain structure. The Ag(I) ion is linearly coordinated by two dipyrazin-2-ylamine ligands through two pyrazine N atoms. (ClO(4) (-))⋯π(pyrazine) [O⋯centroid distances of 3.612 (3) and 3.664 (1) Å] and...
متن کاملCrystal structure of catena-poly[[(N,N-diethyl-3-mesitylsulfonyl-1H-1,2,4-triazole-1-carboxamide-κN 1)silver(I)]-μ-nitrato-κ3 O,O′:O]
The reaction of silver nitrate and cafenstrole (N,N-diethyl-3-mesitylsulfonyl-1H-1,2,4-triazole-1-carboxamide), a triazole herbicide, leads to the title coordination polymer, [Ag(NO3)(C16H22N4O3S)] n , whose asymmetric unit comprises one cafenstrole ligand mol-ecule, one AgI atom and one nitrate ion. The AgI atom, with a distorted trigonal-pyramidal environment, is coordinated by one nitro-gen ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007